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List of some of the most popular Batman villains...will any of these surface in Batman 3?? Many have their money on the Riddler & Two-Face making appearances (a new Joker will probably not make an appearance considering the passing of Heath Ledger).
The Joker The Joker is a master criminal, a violent sociopath, who causes chaos and commits crimes for his own amusement. Wizard magazine rated Joker as the greatest villain of all time. 
Heath Ledger as The Joker in The Dark Knight 
Jack Nicholson as The Joker in Batman
Harvey "Two-Face" Dent Former District Attorney of Gotham City, Harvey "Two-Face" Dent, now disfigured on half of his face, chooses peoples fate with a flip of a coin. 
Aaron Eckhart as Two-Face in The Dark Knight 
Tommy Lee Jones as Two-Face in Batman Forever
Mr. Freeze Mr. Freeze (Dr. Victor Fries) was formerly a scientist and is an expert on cryonics. He tried to cryopreserve his stricken wife Nora Fries until a cure was found to her disease. During the process, an accident caused his body to function only below freezing point, requiring he wear a special self-contained refrigeration suit. He uses similar ice technology for weapons.  Arnold Schwarzenegger as Mr. Freeze in Batman and Robin Penguin The Penguin (Oswald Chesterfield Cobblepot), a short round man with a long pointed nose, fancies himself a gentleman of crime. He usually wears a tuxedo, top hat, and monocle, and carries any variety of umbrellas which have various hidden functions such as vehicles or weapons. 
Danny DeVito as Penguin in Batman Returns
Scarecrow Scarecrow (Prof. Jonathan Crane), an insane scientist and psychiatrist, specializes in the nature of fear. Dressed symbolically as a scarecrow, he employs special weapons, equipment and techniques designed to use fear to his advantage in his crimes.  Cillian Murphy as Scarecrow in Batman Begins Riddler The Riddler (Edward Nygma) is a criminal mastermind who has a strange compulsion to challenge Batman by leaving clues to his crimes in the form of riddles and puzzles. 
Jim Carrey as Riddler in Batman Forever
Poison Ivy Poison Ivy (Pamela Lillian Isley), a former student of advanced botanical biochemistry, employs plants of all varieties and their derivatives in her crimes. She has the ability to control/manipulate all plant life and is immune to all poisons and toxins. She is often described as fanatical about defending plants from other humans, even being willing to murder for her beliefs. She also has a severe love/hate relationship with Batman. In some instances she claims to love him, in other encounters she functions as an ally, and at other times she is more than willing to kill him. 
Uma Thurman as Poison Ivy in Batman and Robin Catwoman Catwoman (Selina Kyle), starting as a criminal who wore a cat-themed costume and often operated as a burglar, has a love/hate relationship with Batman. For years, she skirted on the edge between villain and antiheroine. However, she has largely reformed in recent years, adopting the role of the guardian of Gotham's crime-infested East End, though she still comes into conflict with Batman on occasion. She has also been known to take revenge upon those who do crimes against animals, especially large cats. 
Michelle Pfeiffer as Catwoman in Batman 
Halle Berry as Catwoman in Catwoman
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